Solid-Liquid Phase Transfer Catalysis and Microwave-Assisted Green Synthesis of Tetracyclone

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AuteurKASSEHIN, URBAIN C
AuteurGBAGUIDI, AHOKANNOU FERNAND
AuteurCARATO, PASCAL
AuteurMCCURDY, CHRISTOPHER R
AuteurACCROMBESSI, GEORGES C
AuteurPOUPAERT, JACQUES H
Date d'ajout2026-06-02T16:06:57Z
Date de disponibilite2026-06-02T16:06:57Z
Date de publication2015
ResumeA green synthesis of tetracyclone (2, 3, 4, 5-tetraphenyl-2, 4-cyclopentadien-1-one) has been conceived and executed on the basis of a rationale design. Three separate, “green” processes to synthesize tetracyclone were undertaken to compare homogeneous and heterogeneous reaction conditions as well as to examine the efficacy of microwave enhancement and the utility of phase transfer catalysis. Our mechanistically-based approach involves a unique solid-liquid phase transfer catalysis, microwave activation, and nucleophilic catalysis involving anthranilic acid as a green catalyst. Use of these methods collectively resulted in a yield of 82% for the title compound with a minimal resultant waste stream.
DOI10.5923/j.ajoc.20150505.02
Autre identifiantBECDB-1583
URIhttps://dspace.uac.bj/handle/123456789/1721
Languefr
Fait partie deAmerican Journal of Organic Chemistry
SujetTetracyclone (2
Sujet3
Sujet4
Sujet5-tetraphenyl-2
Sujet4-cyclopentadien-1-one)
SujetMicrowave-Activation
SujetTetracyclone thiosemicarbazone derivatives
SujetDiels–Alder-Reaction
SujetNucleophilic Catalysis
TitreSolid-Liquid Phase Transfer Catalysis and Microwave-Assisted Green Synthesis of Tetracyclone
TypeArticle

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